I have had orders sit for three days before shipping out. Check back later this evening and if no sign of shipping I would phone CS and ask what the hold up is.
I can have stuff sit at 'in process' for days as well, last week was a prime example, I ordered the stamp TSV & a set of Patchwork Pals that was on Love Surprise, the Patchwork Pals was ordered hours before the stamp TSV as I had swithered and swithered most of the day about it, the TSV stamps were sent the next day, the Patchwork Pals were sent 3 days later. There's no rhyme or reason to how they send items out.
I have had things stuck "In Process" for a whole week before - they do eventually turn up but goodness knows what takes them so long, I think they must go out and mine the silver themselves or something :dull: (I only ever order jewellery from QVC).